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Deepwater Horizon Spill Response Solution HA-8-6-10

 

By Anthony J. Sanders

sanderstony@live.com

 

On April 20, 2010, the Deepwater Horizon oil platform, located in the Mississippi Canyon about 40 miles off the Louisiana coast, suffered a catastrophic explosion; it sank a day-and-a-half later.  At the time of the explosion, the Deepwater Horizon was drilling an exploratory well at a depth of approximately 5,000 feet (1,500 m) in the Macondo Prospect, in United States waters about 41 miles (66 km) off the Louisiana coast in the Gulf of Mexico.  The rig was in the final phases of drilling a well in which casing is cemented in place, reinforcing the well. At approximately 10:00 p.m. on April 20, 2010, a blowout preventer failed and an explosion occurred on the rig and she caught fire. Eleven people died and seven workers were airlifted to the Naval Air Station in New Orleans and were then taken to hospital. Support ships sprayed the rig with water in an unsuccessful bid to douse the flames. The Deepwater Horizon sank on April 22, 2010, in water approximately 5,000 feet (1,500 m) deep, and has been located resting on the seafloor approximately 1,300 feet (400 m) (about a quarter of a mile) northwest of the well.  The resulting undersea gusher, conservatively estimated to exceed 20 million gallons as of early June, 2010, is already the worst oil spill in US history, eclipsing the Exxon Valdez, but far smaller than the Gulf War oil spill that leaked as much as 36 billion gallons in 1991, and likely to be on par with most major spills over the past three decades.

 

Although initial reports indicated that relatively little oil had leaked, by April 24 it was discovered that approximately 1,000 barrels (42,000 gallons) of oil per day were issuing from the wellhead, a mile below the surface on the ocean floor. By April 29, the U.S. Government revised their estimate to approximately 5,000 barrels of oil per day (210,000 gallons).  A research vessel commissioned by NOAA to scour the area discovered evidence of a second oil leak, “a gigantic plume” about five to seven miles from the initial leak that BP has focused on fixing, so large that the initial one is “minor: in comparison. The oil field the Deepwater Horizon had tapped is said to be the second largest deposit in the world, covering an estimated 25,000 square miles, from the inlands of Alabama, Florida, Louisiana and Texas.  The oil deposit is so large it could produce 500,000 barrels of a day for more than a decade, 218 x 1015 barrels.  Part of the reason the well exploded is because the site also contains large deposits of natural gas. It is estimated that the well is currently leaking 12,000 to 19,000 barrels a day.  At 42 gallons a barrel, there are 504,000- 798,000 gallons leaking into the Gulf everyday and unofficial estimates range as high as 4.2 million gallons of oil and gas a day.

 

Estimated Volume of Spill April 20 – Aug 20, 2010

Volume of Oil Spill Low - High

April 20

April 20 – May 20     30 days

May 21 – June 20                  60 days

June 21 – July 21      90 days

July 21- Aug. 20  120 days

Tons

1,637 – 2,592

49,110 – 77,760

98,220 – 155,520

147,330 – 233,280

196,560 – 311,040

Barrels

12,000 – 19,000

360,000 – 570,000

720,000 - 1,140,000

1,080,000 – 1,710,000

1,440,000 – 2,280,000

Gallons

504,000 – 798,000

15,120,000 – 23,940,00

30,240,000 – 47,880,000

45,360,000 – 71,820,000

60,480,000 – 95,760,000

* One tonne of crude oil is roughly equal to 308 US gallons, or 7.33 barrels; One Barrel Equals 42 gallons and 0.136 tons at 60 degrees Fahrenheit                                                                                         Source: Examiner.com National. NOAA projections for BP oil spill (Sliding Scale, Digital Image 3) http://www.examiner.com/x-33986-Political-Spin-Examiner~y2010m6d3-NOAA-projections-for-BP-oil-spill-is-world-wide-catastrophe

 

Six weeks to the day after Deepwater Horizon sank, and five days after BP and the government gave up hope for killing the well with blasts of drilling mud, the top hat offered the best chance so far of capturing the leaking oil before it can pollute the gulf further.  The first attempt at containment in mid-May went awry because the large dome lowered over the main leak in the pipe had no mechanism for limiting the amount of water mixing with the oil and gas. The very cold water and gas combined to form slushy methane hydrates that clogged the dome and made it buoyant, so that it wanted to float away from the leak.  On the night of June 3rd BP engineers guided a containment dome onto the hydrocarbon geyser shooting from the Gulf of Mexico oil well in an attempt to capture the leaking oil and funnel it to a ship on the surface.  The government has estimated that the flow rate from the well could increase 20 percent with the bent pipe no longer partially constricting the oil and gas.  The top hat is however estimated to catch as much as 30 percent of leaking oil, siphoning 11,000 barrels of petroleum a day to a drilling ship above, so the result in sum is mitigating.  It is possible that engineers can improve the top hat to the point the well can be used normally or cemented over and sealed.  A relief well is however expected to be completed in August that will theoretically relieve the pressure or if conventional methods fail facilitate a nuclear explosive to be placed to seal the well.

 

Nothing has gone according to plan in the subsea environment as, on the surface, the oil has hit more than 100 miles of Louisiana shoreline. After brushing a barrier island in Alabama, it is poised to tar the white sand beaches of the Florida Panhandle and beyond to the Atlantic coast, to Maine and out to sea, but at more diffuse rates of concentration of oil in the water. The area of the gulf closed to fishing is now larger than the state of Florida.  As of June 4th NOAA had closed 78,182 square miles of waters to fishing, approximately 32 percent of Gulf of Mexico federal waters.  21 different species of marine mammals inhabit the Northern Gulf of Mexico.  282 turtles verified from April 30 to June 4, a total of 236 turtles stranded dead, 21 stranded alive.  From April 30 to June 4, 30 dead dolphins have stranded within the designated spill area and one live dolphin stranded, but died on the beach. So far, one of the 31 dolphins had evidence of external oil, but because it was found on an oiled beach, it was difficult to determine whether the animal was covered in oil prior to its death or after its death. 

 

Source: Examiner.com National. NOAA digital sliding scale projections for BP oil spill (Video) http://www.examiner.com/x-33986-Political-Spin-Examiner~y2010m6d3-NOAA-projections-for-BP-oil-spill-is-world-wide-catastrophe

 

Oil spill model systems are used by industry and government to assist in planning and emergency decision making. Of critical importance for the skill of the oil spill model prediction is the adequate description of the wind and current fields. NOAA's Office of Response and Restoration uses Environmental Sensitivity Index (ESI) maps made up of information within the following three categories: shoreline type, and biological and human-use resources.  NOAA updates these maps daily to inform the fishing industry which waters are closed to fishing, the animal rescue crews where injured animals are likely to be found and to inform the Natural Resource Damage Assessment (NRDA).  Under the 1990 Oil Pollution Act (OPA), a Natural Resource Damage Assessment (NRDA) is a legal process to determine the type and amount of restoration needed to compensate the public for harm to natural resources and their human uses that occur as a result of an oil spill.   The trustees seek from the responsible party the costs of conducting the assessment and restoration planning.  The trustees also seek damages to implement the restoration, and if the responsible party does not agree to damages, the trustees and/or the United States may bring suit or submit a claim for damages to the Oil Spill Liability Trust Fund (Fund), administered by the USCG’s National Pollution Funds Center.

 

The oil slick spreading from the Deepwater Horizon disaster threatens fisheries, tourism and the habitat of hundreds of bird species. Oil spills deeply impact the ecosystem they contaminate.  The oil penetrates bird plumage, reducing its insulating ability, and so making the birds more vulnerable to temperature fluctuations and much less buoyant in the water. It also impairs birds' flight abilities to forage and escape from predators. As they attempt to preen, birds typically ingest oil that covers their feathers, causing kidney damage, altered liver function, and digestive tract irritation. This and the limited foraging ability quickly cause dehydration, and metabolic imbalances. Hormonal balance alteration including changes in luteinizing protein can also result in some birds exposed to petroleum. Most birds affected by an oil spill die unless there is human intervention.  Marine mammals exposed to oil spills are affected in similar ways as seabirds. Oil coats the fur of Sea otters and seals, reducing its insulation abilities and leading to body temperature fluctuations and hypothermia. Ingestion of the oil causes dehydration and impaired digestions.  Because oil floats on top of water, less light penetrates into the water, limiting the photosynthesis of marine plants and phytoplankton.  This, as well as decreasing fauna populations, affects the food chain in the ecosystem, including fish.

 

NOAA Fishery Closure Area June 4, 2010

Fishery Closure Boundary as of June 4, 2010. Closure area may be updated daily as necessary.

Source: NOAA. June 4, 2010. Closure area updated daily as necessary High resolution [pdf]

 

NOAA works closely with the U.S. Food and Drug Administration and the states to ensure seafood safety, by closing fishing areas where tainted seafood could potentially be caught, and assessing whether seafood is tainted or contaminated to levels that pose a risk to human health. The Official Deepwater Horizon Response Unified Command receives calls about Report oiled shoreline or request volunteer information: (866) 448-5816 and oiled wildlife at (866) 557-1401 and is believed to begin their count from May 4th when NOAA began collecting animals.  The daily updated report indicates that of the 820 birds collected, 223 were alive, 597 were dead and 28 were released. Of 289 sea turtles, 46 were alive, 243 were dead and 3 were released.  Of 33 sea mammals, including dolphins, collected, 2 were alive, 30 were dead, and none were released.  One reptile was collected alive.  Most of the dead animals were discovered without visible signs of being oiled. 

 

While there might be skepticism of the danger of the oil spill to wildlife regarding natural causes of death one should probably err on the side of caution in regards to the danger of consuming seafood caught in affected areas where there was no visible signs of oil pollution.  A recent surveying mission of the Eastern Gulf by the Deepwater Horizon Response crew indicated that a small sheen, one-ten millionth of a meter thick, could be observed from the air although it was not apparent to those below in boats.  As the oil floats along the current to the East Gulf of Florida, and ultimately the Atlantic, diluted oil might contaminate the food chain farther than the eye can see.  Consumers are cautioned to avoid Gulf and Atlantic seafood.  Louisiana is the largest seafood producer in the lower 48 states, with annual retail sales of about $1.8 billion, 1.1% of the $140 billion GSP of 2007 recreational fishing generates about $1 billion in retail sales a year, $737 million of that sport fishing according to the state, facing a 2% economic contraction.

 

Fishermen who wish to contact BP about a claim should call 800-440-0858.  BP said today it will be sending a second advance payment during June to individuals and businesses along the Gulf Coast to compensate for the loss of income or net profit due to the cleanup of the Deepwater Horizon Incident in the Gulf of Mexico.  With the second advance payments, BP estimates it will have spent about $84 million for loss of income or net profit through June, based on the claims it has received to date. This number will grow as additional claims are filed. Fishing boats are encouraged to call the Unified Command at 281-366-5511 to convert under the Vessels of Opportunity Program, in order to be paid and have their ships decontaminated by BP.  According to NOAA, there are approximately 5.7 million recreational fishermen in the Gulf of Mexico region who took 25 million fishing trips in 2008. Commercial fishermen in the Gulf harvested more than 1 billion pounds of fish and shellfish in 2008. 

 

An oil spill is the release of a liquid petroleum hydrocarbon into the environment due to human activity, and is a form of pollution. The term often refers to marine oil spills, where oil is released into the ocean or coastal waters.  Most human-made oil pollution comes from land-based activity, but public attention and regulation of oil spills has tended to focus most sharply on seagoing oil tankers.  Spills take months or even years to clean up. Many spills are contained and cleaned up by the party responsible for the spill; some spills require assistance from local and state agencies, and occasionally, the federal government. Oil also enters the marine environment from natural oil seeps.  By observing the thickness of the film of oil and its appearance on the surface of the water, it is possible to estimate the quantity of oil spilled. If the surface area of the spill, and the thickness of the film, is also known, the total volume of the oil can be calculated.  Alternatively if the total volume of oil and surface area of the spill are known the thickness of the film can be predicted, although there are other variables such as wind, current and degradation of the oil.

Oil Spill Film Thickness Observation Chart

 

Film thickness

Quantity spread

Appearance

in

mm

gal/sq mi

L/ha

Barely visible

0.0000015

0.0000380

25

0.370

Silvery sheen

0.0000030

0.0000760

50

0.730

First trace of color

0.0000060

0.0001500

100

1.500

Bright bands of color

0.0000120

0.0003000

200

2.900

Colors begin to dull

0.0000400

0.0010000

666

9.700

Colors are much darker

0.0000800

0.0020000

1332

19.500

Source: Environmental Protection Agency

 

The environmental science experiment of the restoration operation involves balancing the utility of clean-up products listed in the National Contingency Plan Subpart J with the capacity of the ecosystem to biodegrade and absorb such chemicals, while coordinating common sense solutions utilizing human labor.  The major chemical interventions used to clean up oil spill are dispersants that act as detergents and allow small oil globules to drift away on the water.  Dispersents are questionable because the dispersed oil particles, that look like plankton, float under the booms and are probably ingested by plankton eaters and thereby the food chain.  Bio-remediation microorganism and biological agents have been proven to dramatically speed up the decomposition of hydrocarbons through a bloom of hydrocarbon eating bacterial life.  On the practical side, labor, boats can herd oil slicks with booms and strew sorbent, primitively hay, whereas cat litter would sink, and skim the oil soaked hay off the water, load it onto a trash barge and remove the contaminated debris to environmentally sound sites inland.  Through hard work the damage caused by the oil spill on the shoreline and on the currents can be minimized.  When oil reaches the shoreline workers generally use surface washing agents to remove the chemicals and dispose of the contaminated surface material.  This is however difficult to do, while the oil is still leaking, and the exposed fresh soil is likely to be re-contaminated with oil, but again to minimize damage the restoration effort should be labor intensive from the beginning and booms should be placed defensively around shorelines and sensitive ecosystems, such as oyster colonies, protected with underwater fences made of oil absorbent material.   

 

Toxicity and Effectiveness of Dispersants

 

Product
(1:10 Product-to-No. 2 Fuel Oil ratio)

Toxicity
(LC50 values in ppm)

Effectiveness (%)

Menidia
(96-hr)

Mysidopsis
(48-hr)

Prudhoe Bay
Crude Oil

South Louisiana
Crude Oil

Average of
Crude Oils

BIODISPERS

5.95

2.66

51.00

63.00

57.00

COREXIT®EC9500A

2.61

3.40

45.30

54.70

50.00

COREXIT®EC9527A

4.49

6.60

37.40

63.40

50.40

DISPERSIT SPC 1000™

7.90

8.20

40.00

100.00

73.00

FINASOL OSR 52

5.40

2.37

32.50

71.60

52.10

JD-109

3.84

3.51

26.00

91.00

58.50

JD-2000™

3.59

2.19

60.40

77.80

69.10

MARE CLEAN 200

42.00

9.84

63.97

84.14

74.06

NEOS AB3000

57.00

25.00

19.70

89.80

54.80

NOKOMIS 3-AA

34.22

20.16

63.20

65.70

64.50

NOKOMIS 3-F4

100

58.40

62.20

64.90

63.55

SAF-RON GOLD

9.25

3.04

84.80

53.80

69.30

SEA BRAT #4

23.00

18.00

53.55

60.65

57.10

SEACARE ECOSPERSE 52 (see FINASOL®OSR 52)

5.40

2.37

32.50

71.60

52.10

SEACARE E.P.A. (see DISPERSIT SPC 1000™)

7.90

8.20

40.00

100.00

73.00

SF-GOLD DISPERSANT (see SAF-RON GOLD)

9.25

3.04

84.80

53.80

69.30

ZI-400

8.35

1.77

50.10

89.80

69.90

ZI-400 OIL SPILL DISPERSANT (see ZI-400)

8.35

1.77

50.10

89.80

69.90

Source: Environmental Protection Agency. National Contingecy Plan. Subpart J. Toxicity and Effectiveness Summaries. http://www.epa.gov/emergencies/content/ncp/tox_tables.htm

 

Dispersants act as detergents, clustering around oil globules and allowing them to be carried away in the water. This improves the surface aesthetically, and mobilizes the oil. Smaller oil droplets, scattered by currents, may cause less harm and may degrade more easily. But the dispersed oil droplets infiltrate into deeper water and can lethally contaminate coral, oyster fields and other underwater ecosystems. Recent research indicates that some dispersant are toxic to corals. A sheen is usually dispersed (but not cleaned up) with detergents which makes oil settle to the bottom. Oils that are denser than water, such as Polychlorinated biphenyls(PCBs), can be more difficult to clean as they make the seabed toxic.  When this crisis occurred, Coast Guard and EPA granted BP authorization to use an approved dispersant on oil present on the surface of the water in an effort mitigate the impact of the spill. Should data indicate that the dispersants are causing significant environmental damage that outweighs the benefits of their use, EPA and the Coast Guard reserve the right to discontinue use.  Although the crude oil is more toxic than the authorized dispersants, much is unknown about the long term environmental impacts of dispersants when used in these unprecedented volumes on the surface and in the subsea. Because of this and due to the effectiveness of subsea applications, EPA and the U.S. Coast Guard directed BP to significantly ramp down their use of dispersants. BP has complied and has significantly reduced dispersant use.  The E.P.A. approved dispersant is SEACARE E.P.A. (see DISPERSIT SPC 1000™) with a 100% effectiveness rating and low toxicity.

 

Toxicity and Effectiveness of Bioremediation Agents

 

Product
(1:10 Product-to-No. 2 Fuel Oil ratio)

Toxicity*
(LC50 values in ppm)

Effectiveness (28 day)

Menidia (96-hr)

Mysidopsis (48-hr)

Alkanes 
Reduction (%)

Aromatics
Reduction (%)

B&S INDUSTRIAL (see STEP ONE)

NA

NA

44.03

54.51

BET BIOPETRO

NA

NA

99.00

67.00

BILGE CLEAR (see S-200)

25.33

17.67

98.00

10.40

BIOWORLD BIOREMEDIATION TREATMENT PRODUCTS

13.90

7.10

97.00

88.00

GENISIS WE-F (see OPPENHEIMER FORMULA)

NA

NA

89.10

38.20

INIPOL EAP 22 (no longer manuf.)

125.00

35.00

93.87

23.25

JE1058BS

8.68

2.44

92.6

39.0

LAND AND SEA RESTORATION PRODUCT 001 (VELITE)

NA

NA

42.92

31.92

MICRO-BLAZE®

NA

NA

94.10

47.60

MIGHTY MIKE BPT (see OPPENHEIMER FORMULA)

NA

NA

89.10

38.20

NATURAL ENVIRO 8000 BIOREMEDIATION (see OPPENHEIMER FORMULA)

NA

NA

89.10

38.20

OPPENHEIMER FORMULA

NA

NA

89.10

38.20

OIL SPILL EATER II (OSE II)

NA

NA

89.80

89.60

PETRO-TREAT (see OPPENHEIMER FORMULA)

NA

NA

89.10

38.20

PRISTINE SEA II (no longer manuf.)

NA

NA

NA

NA

S-200

25.33

17.67

98.00

10.40

S-200C (see S-200)

25.33

17.67

98.00

10.40

SHEENCLEAN (see S-200)

25.33

17.67

98.00

10.40

SPILLREMED (MARINE)®

37.50

22.40

97.00

47.00

STEP ONE

NA

NA

44.03

54.51

SYSTEM E.T. 20

NA

NA

99.10

77.00

*VB591™, VB997™, BIONUTRIX®

NA

NA

96.80

73.10

WMI-2000

NA

NA

60.30

33.30

Source: Environmental Protection Agency. National Contingecy Plan. Subpart J. Toxicity and Effectiveness Summaries. http://www.epa.gov/emergencies/content/ncp/tox_tables.htm

 

The most scientific method of cleaning up oil spills is known as Bio-remediation.  In bio-remediation microorganisms or biological agents are used to break down or remove oil.  For instance, the human-made, genetically engineered bacterium from the genus Pseudomonas, capable of breaking down crude oil, whose patent was upheld by the U.S. Supreme Court in Diamond, Commissioner of Patents and Trademarks v. Chakarbarty 447 U.S. 303 (1980).   To accelerate the bioremediation process Oleophilic, hydrophobic chemical, containing no bacteria, which chemically and physically bonds to both soluble and insoluble hydrocarbons are released. The bio-remediation accelerator acts as a herding agent in water and on the surface, floating molecules to the surface of the water, forming gel-like agglomerations. By over spraying sheen with bio remediation accelerator, sheen is eliminated within minutes. Whether applied on land or on water, the nutrient-rich emulsion, creates a bloom of local, indigenous, pre-existing, hydrocarbon-consuming bacteria. Those specific bacteria break down the hydrocarbons into water and carbon dioxide, with EPA tests showing 98% of alkanes biodegraded in 28 days; and aromatics being biodegraded 200 times faster than in nature.  They however have the potential to alter the ecosystem.  The E.P.A. offers a variety of competitive bio-remediation solutions with Bioworld Bioremediation Treatment Products getting their best recommendation.

 

Toxicity of Surface Washing Agents

 

Product
(1:10 Product-to-No. 2 Fuel Oil ratio)

Toxicity
(LC50 values in ppm)

Menidia (96-hr)

Mysidopsis (48-hr)

AQUACLEAN

6.50

2.10

BG-CLEAN™ 401

13.10

2.86

BIOSOLVE® HYDROCARBON MITIGATION™ AGENT

7.40

1.30

CLEAN SPLIT (see SPLIT DECISON SC)

0.25

2.06

CN-110

7.40

1.19

COREXIT® EC7664A

15.16

18.34

COREXIT® EC9580A

13.20

9.06

CYTOSOL

24.30

7.00

DO ALL #18

9.38

0.57

DUO-SPLIT (see SPILT DECISION SC)

0.25

2.06

E-SAFE©

8.77

14.20

ENVIROCLEAN

8.13

1.76

F-500

<10.00

32.00

FIREMAN'S BRAND SPILLCLEAN (see SPILLCLEAN)

3.30

1.30

FM-186-2SW (voluntary removal)

160.70

329.90

GOLD CREW SW

6.34

2.70

MICRO CLEAN (see NATURE'S WAY HS)

3.91

1.07

NALE-IT

3.82

1.84

NATURE'S WAY HS

3.91

1.07

NATURE'S WAY PC (see NATURE'S WAY HS)

3.91

1.07

NOKOMIS 5-W

3.07

2.24

PETRO-CLEAN

115.00

105.00

PETRO-GREEN ADP-7

10.95

1.12

PETROTECH 25

3.40

1.00

POWERCLEAN (see NATURE'S WAY HS)

3.91

1.07

PREMIER 99

8.20

2.50

PROCLEANS

4.78

11.68

SC-1000™

4.72

2.13

SHEEN-MAGIC©

7.82

5.75

SIMPLE GREEN®

8.30

4.40

SPILLCLEAN

3.30

1.30

SPILLCLEAN ["Concentrate"] (see SPILLCLEAN)

3.30

1.30

SPLIT DECISION SC

0.25

2.06

SUPERALL #38 (see TOPSALL #30)

4.60

5.00

SX-100 (voluntary removal)

26.00

32.00

TOPSALL #30

4.60

5.00

Source: Environmental Protection Agency. National Contingecy Plan. Subpart J. Toxicity and Effectiveness Summaries. http://www.epa.gov/emergencies/content/ncp/tox_tables.htm

 

The lay man will have to watch and wait to determine which solutions are effective and which are mad science.  In some cases, natural attenuation of oil may be most appropriate, due to the invasive nature of facilitated methods of remediation, particularly in ecologically sensitive areas.  There are common sense solutions to an oil spill.  The most logical method is a controlled burning to effectively reduce the amount of oil in water, but it can only be done in low wind, causes air pollution and can burn coastal flora.  Oils dispersed with detergents and other oils denser than water are cleaned up by the expensive process of dredging.  Skimming is most the effective method of environmental reclamation for the converted fishing vessels and barges.  Skimming requires calm waters and is reliant upon solidifying the oil through the use of sorbents, large absorbents that absorb oil, which is then herded by Booms: large floating barriers that round up oil and lift the oil off the water.  The boats then remove the debris.  Workers on the beaches pick up tar balls, use vacuums, detergents, scrubbers, water, shovels and road equipments to manually remove oil and oil contaminated debris from beaches and water surfaces.  It is left to the volunteers to test the effectiveness of surface washing agents but the E.P.A. toxicity tests point towards the safest product - Split Decision SC.  It would be nice to see skimming boats in action on the news and hear they promptly dispatched to clean up slicks.

 

Toxicity of Miscellaneous Oil Spill Control Agents; Avoid PES-51

 

Product
(1:10 Product-to-No. 2 Fuel Oil ratio)

Toxicity
(LC50 values in ppm)

Effectiveness (%)

Menidia (96-hr)

Mysidopsis (48-hr)

ELASTOL

8.20

3.70

NA

LIQUID ELASTOL (see ELASTOL)

8.20

3.70

NA

MARI-ZYME (see ZYME-FLOW)

8.70

1.60

NA

PES-51

435.00

14.50

NA

PX 700™

5.65

2.77

NA

SEPARATE (see ELASTOL)

8.20

3.70

NA

UNITED 658 PETRO-ZYME (see ZYME-FLOW)

8.70

1.60

NA

ZYME-FLOW

8.70

1.60

NA

ZYME-TREAT (see ZYME-FLOW)

8.70

1.60

NA

Source: Environmental Protection Agency. National Contingecy Plan. Subpart J. Toxicity and Effectiveness Summaries. http://www.epa.gov/emergencies/content/ncp/tox_tables.htm
 
There are of course a number of experimental products used in oil spill cleanup, about whose effectiveness and toxicity to humans, little is known.  The E.P.A. generally knows about the basic toxicity of such substances in silverside fish, Menidia, and shrimp, Mysidosis, and is probably willing to co-operate in the analysis of alternate technology for human safety.  For instance, animal testing by the E.P.A. warns that PES-51 is a highly toxic oil control agent.  The E.P.A. tests air, water and sediment toxicity.  Marine and shore contractors and other people living or working in affected areas should acquire E.P.A. tests and training in data collection.  People living and working in the disaster area must carefully monitor their own health and society for deterioration.  Medical screenings should be made available people volunteering in the oil spill clean-up, even for a day, free of charge, to better study the effect of oil and moderate exercise on particular conditions.  Petroleum does not seem to aggravate heart disease as does grease and animal fat.  Social insurance and social workers should be made available to help dislocated workers avoid mental health and other injustices of the family or employers.  For a popular and safe clean-up effort, no drug test should be required to work on the shore, nor use while working on public beaches allowed.  To request volunteer information from the state agencies coordinating the volunteer effort call (866) 448-5816.
 
Toxicity of Solidifiers

 

Product
(1:10 Product-to-No. 2 Fuel Oil ratio)

Toxicity
(LC50 values in ppm)

Effectiveness (%)

Menidia (96-hr)

Mysidopsis (48-hr)

ALSOCUP

14.00

10.00

NA

AQUA N-CAP™ POLYMER

22.50

2.13

NA

CIAGENT

5.93

1.73

NA

RAPIDGRAB 2000™

4.07

2.60

NA

WASTE-SET 3200®

552.00

58.00

NA

WASTE-SET 3400®

442.00

36.00

NA

Source: Environmental Protection Agency. National Contingecy Plan. Subpart J. Toxicity and Effectiveness Summaries. http://www.epa.gov/emergencies/content/ncp/tox_tables.htm

 

The Coast Guard, in consultation with EPA and the states, has approved waste management plans outlining how recovered oil and waste generated as a result of the BP oil spill will be managed.  To be effective oil-spill clean-up programs must be able to dispose of oil contaminated debris.   Because of the large quantity of oil contaminated waste effective clean-up programs are limited by the availability of certified disposal.  Crude oil skimmed/collected from the water or spill source must be divided into reclaimable/recyclable oil and E & P waste.  Contaminated shore line material collected, once drained of practically recoverable oil is classified as environmental or industrial waste.  Decontaminated fluid waste from cleaning response vessels, reusable booms and other containers is sorted into reclamation/recyclable and E & P waste.  Non oil contaminated trash is sent to Municipal Waste.  Medical waste from wildlife rehabilitation is medical waste.  Dead or injured wildlife are processed by the U.S. Fish and Wildlife Service.  The E.P.A. recommended chemical solidifiers for oil are Ciagent and Rapid Grab 2000 ™.  Natural sorbents, such as hay, might be more effective sponges, which can be engineered to absorb petroleum and repel water. 

 

Oil drilling is a risky occupation, the extraction of volatile substances sometimes under extreme pressure in a hostile environment is dangerous, accidents and tragedies occur regularly.  The advent of offshore drilling, in 1891, didn’t cause a problem until the wells became deeper and pumping capacity increased, whereupon safety became a serious issue.  Reclaiming oil by hand is not a particularly risky seasonal work by comparison, and no deaths or permanent disabilities amongst clean up crews have been reported.  Between 2001 and 2010 the U.S. Minerals Management Service reported 69 offshore deaths, 1,349 injuries, and 858 fires and explosions on offshore rigs in the Gulf of Mexico alone.  B.P., with 83,900 employees, rarely goes a year without a fatality amongst their employees and never without a death amongst their contractors.  Major catastrophes: In July 1988, 167 people died when Occidental Petroleum's Piper Alpha offshore production platform, on the Piper field in the UK sector of the North Sea, exploded after a gas leak. In March 1980, the 'flotel' (floating hotel) platform Alexander Kjelland capsized in a storm in the North Sea with the loss of 123 lives. In 2001, Petrobras 36 in Brazil exploded and sank five days later, killing 11 people. On April 20, 2010, the Deepwater Horizon platform, 52 miles off-shore of New Orleans, (property of Transocean and leased to BP) exploded, killing 11 people, and sank two days later. 

 

Oil spills of over 100,000 tonnes or 30 million US gallons, ordered by tonnes

 

Spill / Tanker

Location

Date

*Tons of crude oil

BP Deepwater Horizon, oil platform

Gulf of Mexico, US Federal

April 20, 2010

98,000 – 311,040

Exxon Valdez, oil tanker

Prince William Sound, Alaska

1989

35,714

11 million gallons

Fergana Valley

Uzbekistan

March 2, 1992

285,000

Gulf War oil spill

Persian Gulf

January 21, 1991

116,883,116 (36 billion gallons)

ABT Summer

700 nautical miles (1,300 km) off Angola

1991

260,000

Amoco Haven tanker disaster

Mediterranean Sea near Genoa, Italy

1991

144,000

Odyssey

700 nautical miles (1,300 km) off Nova Scotia, Canada

1988

132,000

Castillo de Bellver

Saldanha Bay, South Africa

August 6, 1983

252,000

Nowruz oil field

Persian Gulf

February 1983

260,000

Irenes Serenade

Navarino Bay,Greece

1980

100,000

Ixtoc I oil well

Gulf of Mexico

June 3, 1979–March 23, 1980

454,000–480,000

Atlantic Empress/ Aegean Captain

Trinidad and Tobago

July 19, 1979

287,000

Amoco Cadiz

Brittany, France

March 16, 1978

223,000

Sea Star

Gulf of Oman

December 19, 1972

115,000

Urquiola

A Coruńa,Spain

May 12, 1976

100,000

Torrey Canyon

Scilly Isles,UK

March 18, 1967

80,000–119,000

Source: Wikipedia -* One tonne of crude oil is roughly equal to 308 US gallons, or 7.33 barrels.

 

Almost 14,000 oil spills are reported each year.  Between 2005 and 2009 B.P. spilled an average of between 2- 4.4 million barrels of oil a year.  There are thousands of professionals trained to respond to oil spills around the nation.  Some oil spills are the result of natural seeping from the ground.  Oil spills on water or that seep into the groundwater have the potential to degrade large swatches of the environment.  The Deepwater Horizon oil spill is predicted to be the largest oil spill in US history, larger than the 1989 spill from Exxon Valdez that spilled 11 million gallons of oil into an ecologically sensitive area of the Prince William Sound. One difference between the spills is that in 1989 the cause was an oil tanker which holds a finite amount of oil; this spill is tapped to an underwater oil well which may continue to leak for up to 3 months.  There is reported one significantly larger spill, a thousand times larger than any other, during the Gulf War in 1991 when 36 billion gallons of crude oil were spilled, ostensibly when the fleeing Iraqi army burnt the oil wells.  Of the major spills there is the class of 200,000 tons of oil and the class of 100,000.  As of June 6 the Deepwater Horizon spill is just entering the major spill list.  By August 2010 when BP will be ready to drill a new well, assured to seal the leak, the question will be whether Deepwater Horizon will beat the record of 450-480,000 tons of oil leaked by the unstoppable Ixtoc Gulf of Mexico oil well June 1979 and March 1980?

 

For those not content to wait for conventional oil drilling technology the Nuclear Age Peace Foundation advocated for the "nuclear option".  Similar to what was theoretically used to trigger the recent Haitian and Chilean quakes.  A Russian newspaper, Komsomoloskaya Pravda argued earlier this month Russia had successfully used nuclear weapons to seal oil spills on five occasions in the past.  Jeremy, Hsu the Live Science Senior Editor reported on the 12 May 2010, that weapons labs in the former Soviet Union developed special nukes for use to help pinch off the gas wells. They believed that the force from a nuclear explosion could squeeze shut any hole within 82 to 164 feet (25 to 50 meters), depending on the explosion's power. Holes needed to be drilled to place the nuclear device close to the target wells.  A first test in the fall of 1966 proved successful in sealing up an underground gas well in southern Uzbekistan, and so the Russians used nukes four more times for capping runaway wells.  Experts suggest that a nuclear explosion deep inside a well bore would have little effect on surrounding areas.  If you're 18,000 feet under the sea bed, it basically won’t do anything [on the surface].  If the conventional well fails in August, the leak can be nuked.  Environmental scientists and engineers should look into the plan B.

 

Deepwater Horizon was a fifth-generation, RBS-8D design, ultra-deepwater, dynamically positioned, column-stabilized, semi-submersible drilling rig. This type of rig does the initial drilling, then other rigs are used to produce oil from the completed wells. The rig was 396 feet (121 m) long and 256 feet (78 m) wide and according to Billy Nungesser, the president of Plaquemines Parish, Louisiana, was "one of the largest deep-water off-shore drilling rigs." She could operate in waters up to 8,000 feet (2,400 m) deep, and had a maximum drill depth of 30,000 feet (9,100 m). The rig could accommodate up to 130 crew members. The semi-submersible rig floated to the drilling location. She had pontoons and a column that submerge when they are ballasted with sea water, lowering the rig. The rig is moored in place by anchor chains and computer-controlled propellers.

 

Designed originally for R&B Falcon, Deepwater Horizon was built by Hyundai Heavy Industries in Ulsan, South Korea. Construction started in December 1998 and was delivered in February 2001 after the acquisition of R&B Falcon by Transocean. She was the second semi-submersible rig constructed of a class of two, although the Deepwater Nautilus, her predecessor, is not dynamically positioned. Since arriving in the Gulf of Mexico, Deepwater Horizon was under contract to BP Exploration. Her work included wells in the Atlantis and Thunder Horse fields, a 2006 discovery in the Kaskida field, and the 2009 Tiber oilfield. On September 2, 2009, Deepwater Horizon drilled on the Tiber oilfield the deepest oil and gas well ever drilled with a vertical depth of 35,050 feet (10,680 m) and measured depth of 35,055 feet (10,685 m), of which 4,132 feet (1,259 m) was water.  In 2002, the rig was upgraded with "e-drill," a drill monitoring system whereby technicians based in Houston, Texas, received real-time drilling data from the rig and transmitted maintenance and troubleshooting information to it. 

 

At the time of the explosion, the Deepwater Horizon was drilling an exploratory well at a depth of approximately 5,000 feet (1,500 m) in the Macondo Prospect, in United States waters about 41 miles (66 km) off the Louisiana coast in the Gulf of Mexico. In October 2009, BP extended the contract for Deepwater Horizon by three years, to begin in September 2010. The lease contract was worth US$544 million, a rate of $496,800 per day.  Eni's Devil's Tower located in 5,610 ft (1,710 m) of water, in the Gulf of Mexico, was the world's deepest spar until 2010. The world's deepest platform is currently the Perdido spar in the Gulf of Mexico, floating in 2,438 meters of water. It is operated by Royal Dutch Shell and was built at a cost of $3 billion.  The world's deepest oil platform is the floating Independence Hub which is a semi-submersible platform in the Gulf of Mexico in a water depth of 2,414 metres (7,920 ft).  While not the deepest well in the world, at 5,000 feet (1,500 m) Deepwater Horizon drilled quite deep. 

 

 

Legal Planet reported that the malfunctioning blow-out prevent (BOP) was manufactured in 2001 and because this safety device failed, lawyers assure us, the manufacturer (Cameron out of Houston, Texas) will likely have major liability, as will BP, and Halliburton, to cover for the limited liability of Transocean L.L.C. and the e-drilling monitoring service in Houston, Texas. The BOP is a huge block of steel and valves that that holds the well pipe.  The BOP has the ability to slice through the pipe and seal the well. The BOP used by the Deepwater Horizon was with the rig for nine years and had passed inspection 10 days before the accident.  The $600 million oil rig is Transocean’s. BP leases it for some $500,000 a day. Most of the 100+ people on the rig are Transocean’s.  At the time of the explosion, the rig was actively drilling but was not in production according to a spokesman for Transocean Ltd.  On April 20, 2010, the Deepwater Horizon, an offshore drilling rig owned by Transocean Limited, exploded with at least 126 people onboard.  11 people were killed. At the time of the accident executives were reported to have come aboard to celebrate the high marks the platform had earned on a recent safety inspection. 

 

On April 19, 2010 Halliburton workers had finished pumping cement to fill the space between the pipe and the sides of the hole and had begun temporarily plugging the well with cement; the cement job was finished, and pressure testing occurred. Despite there being problems with the pressure testing, Transocean and BP chose to continue displacing the mud, as if the cement job had been successful. This was a grave error. For cementing to be effective, the right mix must be used, and the cement must have time to harden.  Most blowouts that occur offshore historically are the result of a cementing issue, or a BOP failure.  Deepwater Horizon seems to have been the result of both. According to eyewitnesses, prior to the pressure "kick," no alarms sounded. On April 20, at around 10 p.m. (central time) a fire was reported on the rig. Eleven workers were killed.  The rig had been drilling 8,000 barrels of oil per day, and had 700,000 gallons of diesel fuel on board.  After a large conflagration on April 22 the Deepwater Horizon sank.  Unfortunately, because the Deepwater Horizon now is under the ocean, in 5,000 feet of water, proof of the exact cause of this disaster, will cost hundreds of thousands of dollars to discover. 

 

The Center for Public Integrity, a nonprofit investigative news organization, published an account of Coast Guard logs that indicated the Coast Guard knew within 24 hours of the explosion that the rig's BOP had failed and that the well could leak as much as 8,000 barrels a day. The center obtained the logs from Rep. Darrell Issa (R-Calif.), who said in a statement, "These documents raise new questions about whether the White House was slow to respond to an incident that was quickly recognized by the Coast Guard as a potentially catastrophic threat to the environment."  Until April 23 the Coast Guard reported that no oil is leaking and not until April 24 that the Coast Guard reversed its earlier statement that there was no oil leaking and Guard officials conservatively estimated 1,000 barrels of oil per day are coming out of the well head on the ocean floor, 5,000 feet below water.  On April 28 the Coast Guard announces that 5,000, not 1,000, barrels a day of oil are spilling, citing a new NOAA estimate.  And on May 3 the current worst case scenario of BP, is that sealing the 12-19,000 barrel a day leak might take 2-3 months.

 

The Oil Pollution Act (OPA) was signed into law in August 1990, in response to rising public concern following the Exxon Valdez incident, it has subsequently been amended several times and is much different than when it was written. The OPA improved the nation's ability to prevent and respond to oil spills by establishing provisions that expand the federal government's ability, and through the liability of responsible parties, provides the money and resources necessary, to respond to oil spills. The OPA created the national Oil Spill Liability Trust Fund, which is available to provide up to one billion dollars per spill incident. OPA increased penalties for regulatory noncompliance, broadened the response and enforcement authorities of the Federal government, and preserved State authority to establish law governing oil spill prevention and response. The National Oil and Hazardous Substances Pollution Contingency Plan (NCP) has been expanded in a three-tiered approach whereby the Federal government is required to direct all public and private response efforts for certain types of spill events; Area Committees -- composed of federal, state, and local government officials -- must develop detailed, location-specific Area Contingency Plans; and owners or operators of vessels and certain facilities that pose a serious threat to the environment must prepare their own Facility Response Plans.  Under the National Contingency Plan, EPA is the lead federal response agency for oil spills occurring in inland waters, and the U.S. Coast Guard is the lead response agency for spills in coastal waters and deepwater ports.

 

The Prince William Sound (PWS) Oil Spill Recovery Institute (OSRI) was authorized to identify and develop the best available techniques, equipment, and materials for dealing with oil spills in the Arctic and sub-Arctic marine environments; and, also to determine, document, assess and understand the long range effects of the EXXON Valdez oil spill on the natural resources of Prince William Sound. . . and the environment, the economy and the lifestyle and wellbeing of the people who are dependent on them.  The program has received annual interest earnings from a $22.5 million portion of the National Oil Spill Liability Trust Fund.  The program found that oil is degraded in arctic sediments very slowly; biodegradation was only detectable after a full year of exposure of oil to the sediments.  The North Pacific Marine Research Institute was also created on a more academic note.

 

The Key Provisions of the Oil Pollution Act provides at Title 33 USC (40) §2702, that the responsible party for a vessel or facility from which oil is discharged, is liable for removal costs and damages, including damage to natural resources, to real or personal property, to subsistence use of natural resources, to revenues lost, profits and earning capacity, and the cost of public services used to redress the damage caused by the oil spill.  Under 33 USC (40) §2718 States may impose additional liability (including unlimited liability), funding mechanisms, requirements for removal actions, and fines and penalties for responsible parties.  The administration is keeping close tabs on expenses. The Coast Guard sent BP a bill on June 3rd for $69 million giving it until July 1 to reimburse the government for military, National Guard and federal agency efforts to cope with the oil spill.  As a rule of thumb it costs $1,000 in 1990 dollars to clean up one +/- $70 barrel of oil, if it spills. 

 

We are looking at a spill of one to two million barrels and preliminary damage estimates for BP are already estimated to be around $10 billion for the entire restoration.  The federal government and the four affected States, Louisiana, Alabama, Mississippi and Florida, are due compensation for damages, as are all private claimants whose property or livelihoods were damaged by the oil spill or who materially assisted in the solid waste removal.  The plan is to train more than 4,500 workers in the three states in the Mobile Sector (1,500 in Alabama, 1,500 in Mississippi, and 1,600 in Florida). To date there are 2,946 people trained and ready to be deployed (978 in Alabama, 1,500 in Mississippi, and 468 in Florida.  The clean-up effort is expected to go on until fall after which time the oil particles will be left to biodegrade, a process that will take years.  The majority of the economic damage will result from losses sustained to the fishing and tourism industries.  It will be left to communities to remediate their environments and trust funds should be established to redress long term damage that may result from the spill. 

 

BP Financial Information 2007-2009 in millions

 

2007

2008

2009

Revenues

291,438

367,053

246,138

Profit

21,169

21,666

16,759

Source: BP Financial and Operating Information 2005-2009 http://www.bp.com/assets/bp_internet/globalbp/STAGING/ global_assets/downloads/F/FOI_2005_2009_full_book.pdf

 

It should not be difficult for BP to bear the $10 billion cost of the cleanup.  It will however take more than half of their 2010 profits.  In 2009 BP made $16.76 billion in profits, had a market capitalization of $181 billion, revenues of $239 billion, employing 80,300, not including contractors.  Oil, natural gas and energy revenues declined dramatically in 2009, after a two year surge in oil and energy prices.  Despite a 9-10 percent rise worldwide in 2010 demand versus 2009, demand is still 10 percent below the peak in 2008.  The International Energy Association projected, there will not be much of an increase in exploration and development investments in the next five years.  Hit by investor jitters, oil tumbled 26 percent to a low of $64.24 in intraday trade on May 20, from a year-high of $87.15 a barrel on May 3. On Friday, U.S. crude for July delivery was down 32 cents at $74.31.  BP had been on a rebound in the third quarter 2009, with profits of $4.295 billion, and first quarter 2010, $6.079 billion, from a low of $2.562 billion in the first quarter of 2009.  Provided, the market for petroleum and energy continues to grow in 2010, the Gulf oil spill should not take more than half of their profits.  Not to encourage lax environmental standards, in 2010 BP will show the lowest profit margin since they merged with Amoco in 1998.

 

Top World Oil Producers, Exporters, Consumers, and Importers, 2006

(millions of barrels per day)

 Producers

Total oil
production

 Exporters

Net oil
exports

 Consumers

Total oil
consumption

 Importers

Net oil
imports

 1. Saudi Arabia

10.72

 1. Saudi Arabia

8.65

 1. United States

20.59

 1. United States

12.22

 2. Russia

9.67

 2. Russia

6.57

 2. China

7.27

 2. Japan

5.10

 3. United States

8.37

 3. Norway

2.54

 3. Japan

5.22

 3. China

3.44

 4. Iran

4.12

 4. Iran

2.52

 4. Russia

3.10

 4. Germany

2.48

 5. Mexico

3.71

 5. United Arab Emirates

2.52

 5. Germany

2.63

 5. South Korea

2.15

 6. China

3.84

 6. Venezuela

2.20

 6. India

2.53

 6. France

1.89

 7. Canada

3.23

 7. Kuwait

2.15

 7. Canada

2.22

 7. India

1.69

 8. United Arab Emirates

2.94

 8. Nigeria

2.15

 8. Brazil

2.12

 8. Italy

1.56

 9. Venezuela

2.81

 9. Algeria

1.85

 9. South Korea

2.12

 9. Spain

1.56

10. Norway

2.79

10. Mexico

1.68

10. Saudi Arabia

2.07

10. Taiwan

0.94

11. Kuwait

2.67

11. Libya

1.52

11. Mexico

2.03

 

 

12. Nigeria

2.44

12. Iraq

1.43

 12. France

 1.97

 

 

13. Brazil

2.16

13. Angola

1.36

 13. United Kingdom

 1.82

 

 

14. Iraq

2.01

14. Kazakhstan

1.11

 14. Italy

 1.71

 

 

Source: Energy Information Administration (EIA). Country Energy Profiles. www.eia.doe.gov/emeu/cabs/

 

The Gulf of Mexico contributes 24 percent to the nation's oil output of 8.37 million barrels a day, the third largest oil producing nation in the world.  As the result of high consumption totaling 20.59 million barrels a day the United States is a net importer of 12.22 million barrels a day. The bursting of 20 inch pipe in the Gulf is infitesimal in comparison to the total oil passing through the United States.  The oil spill is however quite significant to the environment and livelihood of people and wildlife in the affected areas.  The $10 billion cost of the cleanup is of minor significance to the oil industry.  Oil and natural gas fuel 9.2 million American jobs, 5.2% of the U.S. total, with a labor income of $558 billion, 6.3% of the U.S. total.  Of those jobs 2.1 million were direct and 7.1 million indirect.  In 2007, the most recent year for which data is available, the industry supported a total value added to the national economy of more than $1 trillion or 7.5% of the U.S. gross domestic product.  Considering the massive quantities of oil transported through the U.S. it is inevitable that there will be spills.  Deepwater Horizon is a massive spill, the worst in U.S. history, whose consequences will depress the fishing and tourism industries in Louisiana, Alabama, Mississippi and Florida dramatically in 2010 and for some years in the future.  Furthermore the environmental quality of the Gulf and even Atlantic may jeopardize the safety of seafood from the region.  Every effort must be made to capture the oil at the leak, or in open waters, before it causes further damage the environment. 

 

Bibliography

 

Achenbach, Joel. BP caps well; effectiveness of 'top hat' unclear. June 4, 2010

 

American Petroleum Institute. The People of the Oil and Natural Gas Industry Are the Backbone of the Out Economy. September 2009 http://www.api.org/aboutoilgas/upload/ECONOMIC_IMPACT_US_TOTAL.pdf  

 

Braddock, Joan F. Biodegradation Potential of Petroleum Hydrocarbons in Beaufort Sea Sediments: Assessment of Long-Range Impacts of Oil Spills (Fellowship). Final Report to the Prince Williams Sound Oil Spill Recovery Institute. November 5, 2001 http://www.pws-osri.org/programs/projects/annual_reports/2000/2001Fellowship-Braddock.pdf

 

British Petroleum. BP to Pay a Second Month of Lost Income Claims: Loss of Income Compensation Totals About $84 Million. June 4, 2010. http://www.bp.com/genericarticle.do?categoryId=2012968&contentId=7062660

 

B.P. Code of Conduct. 1999-2010 http://www.bp.com/sectiongenericarticle.do?categoryId=9003494&contentId=7006600

 

B.P. Financial and Operating Information 2005-2009 http://www.bp.com/assets/bp_internet/globalbp/STAGING/ global_assets/downloads/F/FOI_2005_2009_full_book.pdf

 

Buzzbee, Anthony G. Esq. Mathew Davis v. Transocean Ltd. Transocean Offshore Drilling L.L.C. BP Exploration and Production, Inc. and B.P. P.L.C.  District Court of Harris County, Texas. 151st Judicial District. No. 2010-CV-25752 April 26, 2010

 

Buzzbee, Anthony G. Esq. Transocean/BP Oil Rig Accident and Explosion. Gulf of Mexico. April 20, 2010. http://www.txattorneys.com/transocean-bp-explosion.html

 

Deepwater Horizon Response. Unemployed Hired to Clean Affected Beaches. Mobile, Alabama. June 5, 2010

 

Deepwater Horizon Response.  The Official Site of the Deepwater Horizon Unified Command. Current Operations. http://www.deepwaterhorizonresponse.com/go/doctype/2931/53339/

 

Diamond, Commissioner of Patents and Trademarks v. Chakarbarty 447 U.S. 303 (1980) http://caselaw.lp.findlaw.com/scripts/getcase.pl?court=us&vol=447&invol=303

 

Energy Information Administration (EIA). Country Energy Profiles. www.eia.doe.gov/emeu/cabs/

 

Environmental Protection Agency. Incident Commander U.S. Coast Guard and State of Louisiana. Recovered Oil/Waste Management Plan Houma Incident Command. 22 April 2010 http://www.epa.gov/bpspill/waste/r6_waste_plan.pdf

 

Examiner.com National. NOAA projections for BP oil spill (Sliding Scale, Digital Image 3) http://www.examiner.com/x-33986-Political-Spin-Examiner~y2010m6d3-NOAA-projections-for-BP-oil-spill-is-world-wide-catastrophe

 

National Oceanic and Atmospheric Administration. Office of Response and Restoration. Office of Habitat Conservation. General Counsel for Natural Resources. Deepwater Horizon oil Spill: NOAA NRDA Activities as of May 7, 2010. http://response.restoration.noaa.gov/book_shelf/1959_deepwater-Horizon-NRDA-ORR-web-5-7-10.pdf

 

NOAA. Opens 16,000 Square Miles of Fishing Closed Area in Gulf of Mexico. Closes 2,200-square mile stretch. June 4, 2010

 

Tan, Jennifer; Hussain, Rmathan. Oil industry grapples with risk and volatile prices.  Reuters. Singapore. June 4, 2010

 

United States Code. Title 33 Navigation and Navigable Waters. Chapter 40 Oil Pollution. The Clean Water and Oil Pollution Act (OPA) of 1990. Subchapter I Oil Pollution Liability and Compensation http://uscode.house.gov/download/pls/33C40.txt